三宅由寛

ミヤケヨシヒロ (Yoshihiro Miyake)

基本情報

所属: 兵庫県立大学大学院理学研究科物質科学専攻物質反応解析学部門教授

学位: 博士（工学）(京都大学)

研究者番号: 00347270
J-GLOBAL ID: 201301042462940888
researchmap会員ID: 7000006627

外部リンク: https://www.miyake-organic-lab.com

研究分野

経歴

2022年4月 - 現在

兵庫県立大学大学院理学研究科教授
2013年4月 - 2022年3月

名古屋大学大学院工学研究科有機・高分子化学専攻准教授
2005年7月 - 2013年3月

東京大学大学院工学系研究科総合研究機構助教
2002年7月 - 2005年6月

東京都立大学大学院理学研究科助手
2002年4月 - 2002年6月

科学技術振興事業団博士特別研究員

学歴

1999年4月 - 2002年3月

京都大学工学研究科物質エネルギー化学専攻
1997年4月 - 1999年3月

京都大学工学研究科物質エネルギー化学専攻

受賞

論文

143

Design and Preparation of Molybdenum-Dinitrogen Complexes with Ferrocenyldiphosphine and Pentamethylcyclopentadienyl Moieties as Auxiliary Ligands

Takamasa Miyazaki, Yoshiaki Tanabe, Masahiro Yuki, Yoshihiro Miyake, Kazunari Nakajima, Yoshiaki Nishibayashi

CHEMISTRY-A EUROPEAN JOURNAL 19(36) 11874-11877 2013年9月査読有り
Synthesis, Structure, and Reactivity of Group VI Metal Complexes Bearing Group IV Metallocenyldiphosphine Moieties and a Pentamethylcyclopentadienyl Ligand

Takamasa Miyazaki, Yoshiaki Tanabe, Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 32(6) 2007-2013 2013年3月査読有り
Ruthenium-Triggered Ring Opening of Ethynylcyclopropanes: [3+2] Cycloaddition with Aldehydes and Aldimines Involving Metal Allenylidene Intermediates

Yoshihiro Miyake, Satoshi Endo, Taichi Moriyama, Ken Sakata, Yoshiaki Nishibayashi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 52(6) 1758-1762 2013年査読有り
Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts

Yoshihiro Miyake, Kazunari Nakajima, Yoshiaki Nishibayashi

CHEMICAL COMMUNICATIONS 49(71) 7854-7856 2013年査読有り
Preparation and reactivity of molybdenum-dinitrogen complexes bearing an arsenic-containing ANA-type pincer ligand

Yoshiaki Tanabe, Shogo Kuriyama, Kazuya Arashiba, Yoshihiro Miyake, Kazunari Nakajima, Yoshiaki Nishibayashi

CHEMICAL COMMUNICATIONS 49(81) 9290-9292 2013年査読有り
Direct sp3 C?H Amination of Nitrogen-Containing Benzoheterocycles Mediated by Visible-Light-Photoredox Catalysts

Yoshihiro Miyake, Kazunari Nakajima, Yoshiaki Nishibayashi

CHEMISTRY-A EUROPEAN JOURNAL 18(51) 16473-16477 2012年12月査読有り
Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

Masahiro Yuki, Hiromasa Tanaka, Kouitsu Sasaki, Yoshihiro Miyake, Kazunari Yoshizawa, Yoshiaki Nishibayashi

NATURE COMMUNICATIONS 3 1254. 2012年12月査読有り
Synthesis and Catalytic Activity of Molybdenum-Dinitrogen Complexes Bearing Unsymmetric PNP-Type Pincer Ligands

Eriko Kinoshita, Kazuya Arashiba, Shogo Kuriyama, Yoshihiro Miyake, Ryuji Shimazaki, Haruyuki Nakanishi, Yoshiaki Nishibayashi

ORGANOMETALLICS 31(23) 8437-8443 2012年12月査読有り
Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation

Yoshihiro Miyake, Shin-ichi Ota, Yoshiaki Nishibayashi

CHEMISTRY-A EUROPEAN JOURNAL 18(42) 13255-13258 2012年10月査読有り
Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Propargylic Allylation of Propargylic Alcohols with α,β-Unsaturated Aldehydes

Masahiro Ikeda, Yoshihiro Miyake, Yoshiaki Nishibayashi

Organometallics 31(9) 3810-3813 2012年5月査読有り
Synthesis and Reactivity of Hybrid Phosphido- and Hydrosulfido-Bridged Diruthenium Complexes: Transformations into Diruthenium and Tetraruthenium Complexes Bridged by Phosphido and Sulfido Ligands

Yoshihiro Miyake, Taichi Moriyama, Yoshiaki Tanabe, Satoshi Endo, Yoshiaki Nishibayashi

ORGANOMETALLICS 31(8) 3292-3299 2012年4月査読有り
Ruthenium- and Copper-Catalyzed Enantioseletive Propargylic Alkylation of Propargylic Alcohols with β-Keto Phosphonates

Kazuki Motoyama, Masahiro Ikeda, Yoshihiro Miyake, Yoshiaki Nishibayashi

Organometallics 31(8) 3426-3430 2012年4月査読有り
Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines

Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 31(8) 2953-2956 2012年4月査読有り
Cooperative Catalytic Reactions Using Distinct Transition-Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation

Masahiro Ikeda, Yoshihiro Miyake, Yoshiaki Nishibayashi

CHEMISTRY-A EUROPEAN JOURNAL 18(11) 3321-3328 2012年3月査読有り
Synthesis and Protonation of Molybdenum- and Tungsten-Dinitrogen Complexes Bearing PNP-Type Pincer Ligands

Kazuya Arashiba, Kouitsu Sasaki, Shogo Kuriyama, Yoshihiro Miyake, Haruyuki Nakanishi, Yoshiaki Nishibayashi

ORGANOMETALLICS 31(5) 2035-2041 2012年3月査読有り
Visible-Light-Mediated Utilization of α-Aminoalkyl Radicals: Addition to Electron Deficient Alkenes Using Photoredox Catalysts

Yoshihiro Miyake, Kazunari Nakajima, Yoshiaki Nishibayashi

J. Am. Chem. Soc. 134(7) 3338-3341 2012年2月査読有り
Visible-Light-Mediated Addition of α-Aminoalkyl Radicals Generated from α-Silylamines to α,β-Unsaturated Carbonyl Compounds

Yoshihiro Miyake, Yuya Ashida, Kazunari Nakajima, Yoshiaki Nishibayashi

Chem. Commun. 48(55) 6966-6968 2012年査読有り
Enantioselective Alkylation of β-Keto Phosphonates by Direct Use of Diaryl Methanols as Electrophiles

Masashi Shibata, Masahiro Ikeda, Kazuki Motoyama, Yoshihiro Miyake, Yoshiaki Nishibayashi

Chem. Commun. 48(76) 9528-9530 2012年査読有り
Remarkable Effect of Valence Electrons in Thiolato-Bridged Diruthenium Complexes toward Catalytic Dimerization of α-Methylstyrenes

Yoshihiro Miyake, Taichi Moriyama, Yoshiaki, Tanabe, Gen Onodera, Yoshiaki Nishibayashi

Organometallics 30(21) 5972-5977 2011年11月査読有り
Recent Progress in Catalytic Reactions via Copper-Acetylide Complexes as Key Intermediates

Gaku Hattori, Yoshihiro Miyake, Yoshiaki Nishibayashi

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 69(10) 1086-1098 2011年10月査読有り
Propargylic Substitution Reaction Catalyzed by Group IV (Ti, Zr, Hf)-Ru Heterobimetallic Complexes

Takamasa Miyazaki, Yoshiaki Tanabe, Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 30(11) 3194-3199 2011年6月査読有り
Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

Akiko Yoshida, Gaku Hattori, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANIC LETTERS 13(9) 2460-2463 2011年5月査読有り
Cooperative Catalytic Reactions Using Lewis Acids and Organocatalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols Bearing an Internal Alkyne with Aldehydes

Kazuki Motoyama, Masahiro Ikeda, Yoshihiro Miyake, Yoshiaki Nishibayashi

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (12) 2239-2246 2011年4月査読有り
Synthesis of Group IV (Zr, Hf)-Group VIII (Fe, Ru) Heterobimetallic Complexes Bearing Metallocenyl Diphosphine Moieties and Their Application to Catalytic Dehydrogenation of Amine-Boranes

Takamasa Miyazaki, Yoshiaki Tanabe, Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 30(8) 2394-2404 2011年4月査読有り
Molybdenum-Catalyzed Transformation of Molecular Dinitrogen into Silylamine: Experimental and DFT Study on the Remarkable Role of Ferrocenyldiphosphine Ligands

Hiromasa Tanaka, Akira Sasada, Tomohisa Kouno, Masahiro Yuki, Yoshihiro Miyake, Haruyuki Nakanishi, Yoshiaki Nishibayashi, Kazunari Yoshizawa

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133(10) 3498-3506 2011年3月査読有り
A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

Kazuya Arashiba, Yoshihiro Miyake, Yoshiaki Nishibayashi

NATURE CHEMISTRY 3(2) 120-125 2011年2月査読有り
Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

Akiko Yoshida, Masahiro Ikeda, Gaku Hattori, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANIC LETTERS 13(4) 592-595 2011年2月査読有り
Preparation of Thiolate-Bridged Dinuclear Ruthenium Complexes Bearing a Phosphine Ligand and Application to Propargylic Reduction of Propargylic Alcohols with 2-Propanol

Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 29(22) 5994-6001 2010年11月査読有り
Preparation and Reactivity of a Ruthenium Complex Bearing a 2,6-Bis(trimethylsilyl)benzenethiolate Ligand

Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 29(18) 4148-4153 2010年9月査読有り
Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper-Allenylidene Complexes as Key Intermediates

Gaku Hattori, Ken Sakata, Hiroshi Matsuzawa, Yoshiaki Tanabe, Yoshihiro Miyake, Yoshiaki Nishibayashi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132(30) 10592-10608 2010年8月査読有り
Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols

Keiichiro Kanao, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 29(9) 2126-2131 2010年5月査読有り
Intramolecular Edge-to-Face Aromatic π-π Interaction in Optically Active Ruthenium-Allenylidene Complexes for Enantioselective Propargylic Substitution Reactions

Keiichiro Kanao, Yoshiaki Tanabe, Yoshihiro Miyake, Yoshiaki Nishibayashi

Organometallics 29(10) 2381-2384 2010年5月査読有り
Copper-Catalyzed Diastereo- and Enantioselective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine

Gaku Hattori, Yoshihiro Miyake, Yoshiaki Nishibayashi

CHEMCATCHEM 2(2) 155-158 2010年2月査読有り
Structural, electronic and magnetic properties of Cu(II) complexes of 2-substituted tropones bearing a ferrocenyl group at 5-position

Tohru Nishinaga, Tomoshi Aono, Eigo Isomura, Sayaka Watanabe, Yoshihiro Miyake, Akira Miyazaki, Toshiaki Enoki, Hitoshi Miyasaka, Hiroyuki Otani, Masahiko Iyoda

DALTON TRANSACTIONS 39(9) 2293-2300 2010年査読有り
Cooperative Catalytic Reactions Using Organocatalysts and Transition-Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes

Masahiro Ikeda, Yoshihiro Miyake, Yoshiaki Nishibayashi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 49(40) 7289-7293 2010年査読有り
Catalytic Propargylic Substitution Reactions

Yoshihiro Miyake, Sakae Uemura, Yoshiaki Nishibayashi

CHEMCATCHEM 1(3) 342-356 2009年11月査読有り
Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper-Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

Gaku Hattori, Akiko Yoshida, Yoshihiro Miyake, Yoshiaki Nishibayashi

J. Org. Chem. 74(20) 7603-7607 2009年10月査読有り
Preparation and Protonation of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands

Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 28(19) 5821-5827 2009年10月査読有り
Design and Synthesis of Diphosphine Ligands Bearing an Osmium(II) Bis(terpyridyl) Moiety as a Light-Harvesting Unit: Application to Photocatalytic Production of Dihydrogen

Yoshihiro Miyake, Kazunari Nakajima, Kouitsu Sasaki, Ryuichi Saito, Haruyuki Nakanishi, Yoshiaki Nishibayashi

ORGANOMETALLICS 28(17) 5240-5243 2009年9月査読有り
Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Ruthenocenyldiphosphines

Masahiro Yuki, Tatsuya Midorikawa, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 28(16) 4741-4746 2009年8月査読有り
Ruthenium-Catalyzed Enantioselective Intramolecular Propargylation of Thiophenes with Propargylic Alcohols

Keiichiro Kanao, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 28(9) 2920-2926 2009年5月査読有り
Development of Novel Catalytic Reactions via Ruthenium-Allenylidene Complexes as Key Intermediates

Yoshiaki Nishibayashi, Yoshihiro Miyake, Sakae Uemura

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN 67(5) 437-450 2009年5月査読有り
Remarkable Effect of Halogens on Catalytic Activities of Thiolato-Bridged Diruthenium Complexes in Propargylic Substitution Reactions

Yoshiaki Tanabe, Keiichiro Kanao, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 28(4) 1138-1142 2009年2月査読有り
A DFT Study on the Reaction Pathways for Carbon-Carbon Bond-Forming Reactions between Propargylic Alcohols and Alkenes or Ketones Catalyzed by Thiolate-Bridged Diruthenium Complexes

Ken Sakata, Yoshihiro Miyake, Yoshiaki Nishibayashi

CHEMISTRY-AN ASIAN JOURNAL 4(1) 81-88 2009年査読有り
Ruthenium-Catalyzed Oxypropargylation of Alkenes

Yoshihiro Yamauchi, Yoshihiro Miyake, Yoshiaki Nishibayashi

ORGANOMETALLICS 28(1) 48-50 2009年1月査読有り
Catalytic Cycloisomerization of 1,5-Enynes to 1,3-Cyclohexadienes via Ruthenium Vinylidene Intermediates

Koji Fukamizu, Yoshihiro Miyake, Yoshiaki Nishibayashi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 48(14) 2534-2537 2009年査読有り
Synthesis and Protonolysis of Tungsten- and Molybdenum-Dinitrogen Complexes Bearing Bis(dialkylphosphinobenzene)chromiums as Auxiliary Ligands

Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi

Organometallics 28 5821-5827 2009年査読有り
Ruthenium-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Alcohols

Keiichiro Kanao, Hiroshi Matsuzawa, Yoshihiro Miyake, Yoshiaki Nishibayashi

SYNTHESIS-STUTTGART (23) 3869-3873 2008年12月査読有り
Synthesis and Reactivity of Hybrid Phosphido- and Thiolato-Bridged Diruthenium Complexes

Yoshihiro Miyake, Satoshi Endo, Masahiro Yuki, Yoshiaki Tanabe, Yoshiaki Nishibayashi

ORGANOMETALLICS 27(22) 6039-6042 2008年11月査読有り
Synthesis and reactivity of tungsten- and molybdenum-dinitrogen complexes bearing ferrocenyldiphosphines toward protonolysis

Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi, Issei Wakiji, Masanobu Hidai

ORGANOMETALLICS 27(15) 3947-3953 2008年8月査読有り

MISC

2D共役共有結合有機骨格(COF)の自己組織化による1D電子伝導性ナノチューブへのin-situ変換

LI Zhuowei, 常行恭弘, GHOSH Samrat, 仲里巧, 小田原正浩, 松田若菜, 信岡正樹, CHEN Bin, PAITANDI Rajendra Prasad, 筒井祐介, 田中隆行, 須田理行, 三宅由寛, 忍久保洋, 関修平

日本化学会春季年会講演予稿集(Web) 103rd 2023年
アザインドール骨格を有するオクタアザ[8]サーキュレンの合成

赤堀周平, 加賀敦志, 依光英樹, 忍久保洋, 三宅由寛

日本化学会春季年会講演予稿集(CD-ROM) 100th 2020年
2,7-ジアザピレンおよび2,9-ジアザペロピレンの合成と物性

仲里巧, 中村泰崇, 鎌塚拓人, 松田若菜, 櫻井庸明, 関修平, 忍久保洋, 三宅由寛

分子科学討論会講演プログラム&要旨(Web) 13th 2019年
フェロセニルジホスフィン配位子を有するモリブデン-ニトリド錯体の特異な反応性

宮崎貴匡, 田辺資明, 結城雅弘, 三宅由寛, 西林仁昭

日本化学会講演予稿集 93rd(2) 2013年
含ヒ素ピンサー型配位子を有するモリブデン窒素錯体の合成と反応性

田辺資明, 栗山翔吾, 荒芝和也, 三宅由寛, 西林仁昭

日本化学会講演予稿集 92nd(2) 2012年