堀 恵一

令和二年度宇宙輸送シンポジウム（2021年1月14日-15日. オンライン開催)資料番号: SA6000160011レポート番号: STCP-2020-011

平成25年度宇宙輸送シンポジウム（2014年1月16日-17日. 宇宙航空研究開発機構宇宙科学研究所（JAXA)(ISAS)）, 相模原市, 神奈川県資料番号: SA6000016009レポート番号: STCP-2013-009

平成25年度宇宙輸送シンポジウム（2014年1月16日-17日. 宇宙航空研究開発機構宇宙科学研究所（JAXA)(ISAS)）, 相模原市, 神奈川県資料番号: SA6000016010レポート番号: STCP-2013-010

The cost reduction is currently important for the development of space launch systems. The solid motor side jet system is loaded the low temperature gas generator propellant (GGP) which includes a special purpose material. The combustion gas temperature of GGP should be controlled up to 1400 K because of the system requirement. The objective of this research is to find the substitution of the composition for GGP to reduce the cost. That is why ammonium nitrate (AN) is selected as an oxidizer for GGP. The composition and combustion characteristics of AN based GGP for the launch vehicle side jet system were investigated. The burning rate was measured by the strand burner.

Combustion characteristics of pelletized ammonium dinitramide (ADN) and ADN-based propellants have been studied. Micron-meter-sized particles of Al, Fe2O3, TiO2, NiO, Cu(OH)NO3, Cu and CuO, and nano-meter-sized Al (Alex) and CuO (nanoCuO) were employed as the additives for pelletized ADN. Only nanoCuO and Alex show the remarkable effects, so they are also added to ADN-based propellant. The binder of ADN-based propellant is thermoplastic elastomer (TP), and three kinds of mixtures (TP:ADN = 30:70, 20:80 and 10:90 mass%) were prepared .The burning rates of pelletized ADN and ADN-based propellants were measured under the pressure range from 0.6 to 6.2 MPa, and the surface temperature profiles were obtained about ADN-based propellants. Nano-sized CuO enhanced the burning rate of pelletized ADN. Alex-incorporated ADN burned with flames even at 0.55 MPa under which pure ADN does not form the flame. Burning rate of non-additive ADN-based propellants has extremely high pressure dependency. In the case of TP/ADN (30:70), burning rate jump are found from the critical pressure approximately 3.2MPa. The temperature profiles of TP/ADN (30:70) were measured, and the combustion structure was discussed. Both nanoCuO and Alex improved the burning rate characteristics, and the pressure exponents are 0.54 and 0.76 respectively.